Lanthanide rare earth series cryptate compounds and process for

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2603403, C07F 500, C07F 1506, C07F 1504, C07F 1502, C07F 1300, C07F 1100, C07F 900, C07F 728

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042579554

ABSTRACT:
Novel lanthanide rare earth series cryptate coordination compounds or complexes are described. The compounds are highly kinetically inert in aqueous solution to dissociation of the complexes as a function of time. The compounds are particularly useful as relaxation agents in NMR spectra because of their stability in water or polar organic solvents and are also useful in electrochemistry, synthesis and medicine. A process for the preparation of metal cryptate coordination compounds in general is also described.

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