Laminating adhesive for film/paper microwavable products

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4284752, 428481, 428514, 428516, 428518, 383123, 426111, 426113, 426234, 524502, 524808, B65D 3322, B65D 8500, C08L 3300, B32B 2708

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049119605

ABSTRACT:
Wet laminating adhesives capable of withstanding the stresses encountered during heat sealing operations are prepared from emulsion copolymers consisting essentially of 45 to 80% by weight of a vinyl ester of an alkanoic acid, 10 to 30% ethylene, 5 to 30% of dialkyl maleate, 0.5 to 2% of an N-methylol containing comonomer and 0.5 to 4% of an ethylenically unsaturated mono- or di-carboxylic acid. These specific emulsion copolymers are prepared utilizing standard emulsion polymerization procedures with hydroxyethylcellulose or polyvinyl alcohol as a protective colloid. The emulsion polymers thus produced provide superior wet laminating adhesive properties for use in substrates which are to be formed into microwavable packages or bags.

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