Ladder-like silicone polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

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C106S287160, C528S014000

Reexamination Certificate

active

07022799

ABSTRACT:
There is disclosed a three stage method for the preparation of ladder-like silicone polymers. The first stage comprises hydrolysis and polymerization of alkyltrialkoxylsilane-like monomers to give relatively low molecular weight prepolymers. The second stage comprises dehydrated condensation polymerization of the prepolymers to give high molecular weight polymers. The third stage comprises partial blocking of a proportion of the pendant Si—OH (silanol) groups with a pre-determined sub-stoichiometric amount of a blocking agent. Also disclosed are the prepolymers, polymers and partially blocked polymers so produced.

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