Isotopic separation by photopredissociation

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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204158R, 204DIG11, 55 2, B01J 110

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active

039830209

ABSTRACT:
A monochromatic source excites individual isotopic lines in a well-resolved absorption spectrum for which the upper state is predissociated. Isotopic enrichment is thus achieved in the dissociation products, which may be stable molecules or may be chemically trapped if they are reactive. As an example, isotopic separation of hydrogen and deuterium is performed by exciting formaldehyde with a frequency-doubled ruby laser.

REFERENCES:
patent: 3443087 (1969-05-01), Robieux et al.
patent: 3673406 (1972-06-01), Nief et al.
Mayer et al., Applied Physics Letters, vol. 17, No. 12, (15 Dec. 1970), pp. 516-519.

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