Isotope separation by multiphoton dissociation of methylamine wi

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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204DIG11, B01D 5400, B01J 110

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active

041938550

ABSTRACT:
Methylamine (CH.sub.3 NH.sub.2) is dissociated into CH.sub.3 .multidot. and NH.sub.2 .multidot. radicals when irradiated with the output from an infrared laser. Ammonia (NH.sub.3) is then formed inherently through radical and molecular collisions. By tuning the laser to the appropriate frequency, the dissociation process is isotopically selective. As a consequence, ammonia, or other nitrogen containing compounds, are obtained which are selectively enriched in .sup.14 N or .sup.15 N. Carbon isotopes may be separated with essentially the same technique. .sup.

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