Isotactic specific catalyst for direct production of highly...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

Reexamination Certificate

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C528S421000, C502S150000, C502S171000

Reexamination Certificate

active

07399822

ABSTRACT:
(Salph or methoxy salph) Co (initiating ligand) catalyze homopolymerizing rac-PO to produce pure highly isotactic PPO and rac-1-butylene oxide to produce pure isotactic poly(butylene oxide). A product is unfractionated isotactic PPO of m-dyad content >81%, normally at least 99%.

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Wöltinger, J., et al., “Zeolite-Encapsulated Cobalt Salophen Complexes as Efficient Oxygen-Activating Catalysts in Palladium-Catalyzed Aerobic 1,4-Oxidation of 1,3-Dienes”, Chem. Eur. J. 1999, vol. 5, No. 5, pp. 1460-1467.

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