Isotactic poly(glycidyl nitrate) and synthesis thereof

Details Isotactic poly(glycidyl nitrate) and synthesis thereof Isotactic poly(glycidyl nitrate) and synthesis thereof

1992-08-13

1993-11-23

Kight, III, John

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549510, 549512, 549513, 558483, 5253332, 528408, 528409, 528417, 528403, C07D30336, C07D30100, C08G 6510

Patent

active

052645967

ABSTRACT:
Isotactic poly(glycidyl nitrate) useful in solid propellants is produced by polymerizing chiral (R) glycidyl nitrate or its enantiomer, (S) glycidyl nitrate. Chiral (R) glycidyl nitrate or its enantiomer is prepared by sequential treatment of chiral (S) glycidyl tosylate or its enantiomer with nitric acid and sodium hydroxide. Chiral (S) glycidyl tosylate or its enantiomer, (R) glycidyl tosylate, can be produced by Sharpless epoxidation of allyl alcohol or by direct tosylation or commercially available chiral glycidol. Likewise, chiral (R) glycidyl nitrate or its enantiomer, (S) glycidyl nitrate, can be prepared directly via nitration of (S) or (R) glycidol, respectively.

REFERENCES:
patent: 4885584 (1991-01-01), Millar et al.
patent: 5136062 (1992-08-01), Millar et al.
Kirk-Othmer Ency. of Chem. Tech. 3rd Ed, vol. 15, pp. 841-853.

Affiliated with

Also associated with

Rating

Isotactic poly(glycidyl nitrate) and synthesis thereof does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Isotactic poly(glycidyl nitrate) and synthesis thereof, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Isotactic poly(glycidyl nitrate) and synthesis thereof will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1850532