Isosolanone and solanone intermediates and organoleptic uses

Details Isosolanone and solanone intermediates and organoleptic uses Isosolanone and solanone intermediates and organoleptic uses

1984-06-22

1985-12-24

Waltz, Thomas A.

Compositions

Electrically conductive or emissive compositions

Metal compound containing

252 86, 25217411, 252522A, 424 69, 424 70, C11B 900

Patent

active

045604991

ABSTRACT:
Described is a novel genus of compounds defined according to the structure: ##STR1## wherein Z represents hydrogen, MgX and the moiety having the structure: ##STR2## and X represents chloro, bromo or iodo; as well as the novel compounds defined according to the structures: ##STR3## and mixtures of same shown according to the structure: ##STR4## wherein the wavy lines indicate both cis and trans juxtaposition of the hydrogen and methallyl moieties about the carbon-carbon double bond; uses of same as intermediates in a process for producing isosolanone which is a mixture of compounds having the structures: ##STR5## or shown by the single structure: ##STR6## and solanone which is a mixture of compounds having the structures: ##STR7## or shown by the structure: ##STR8## wherein the wavy lines are indicative of a cis or trans juxtaposition of the hydrogen or 2-propenyl moieties about the double bond; and organoleptic uses of the compounds having the structures: ##STR9##

REFERENCES:
patent: 2838576 (1958-06-01), Normant
patent: 3258497 (1966-06-01), Lemberg
patent: 3700717 (1972-10-01), Kappeler et al.
patent: 3997577 (1976-12-01), von Fraunberg
patent: 4347388 (1982-08-01), Gramlich et al.

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