Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization
Patent
1987-12-17
1988-11-08
Davis, Curtis R.
Chemistry of hydrocarbon compounds
Saturated compound synthesis
By isomerization
585752, 585940, C07C 513
Patent
active
047835753
ABSTRACT:
A C.sub.4 -C.sub.6 feed to an isomerization zone containing substantial amounts of cyclic hydrocarbons is contacted with a high chloride, platinum alumina catalyst to simultaneously open cyclic hydrocarbon rings and isomerize paraffins to more highly branched paraffins. The process can operate at relatively low severity conditions that provide favorable equilibrium conditions for isoparaffin conversion. The ring opening is also obtained without excessive generation of light hydrocarbons. Multiple stage reaction zones may be used to operate the first stage at slightly higher severity than the second stage to maximize ring opening and obtain favorable equilibrium of iso to normal paraffins.
REFERENCES:
patent: 2915571 (1959-12-01), Haensel
patent: 3242228 (1966-03-01), Riordan et al.
patent: 3449264 (1969-06-01), Myers
patent: 3457162 (1969-07-01), Riedl et al.
patent: 3631117 (1971-12-01), Kovach et al.
Schmidt Robert J.
Stine Laurence O.
Davis Curtis R.
McBride Thomas K.
Tolomei John G.
UOP Inc.
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