Isomerization of terpene compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2606755, C07C 526

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active

041089170

ABSTRACT:
Cyclic terpene compounds selected from the class consisting of pinane, alpha-pinene, beta-pinene and mixtures thereof are converted into their corresponding open-chain isomers-e.g., dihydromyrcene, allo-ocimene and myrcene-by thermal isomerization at a temperature of at least 300.degree. C in the presence of a solid material comprising a metal or metal oxide selected from the class consisting of alkali metals, alkaline earth metals, transition metals and mixtures thereof supported on a carrier having a specific surface area in the range of about 0.01 to about 20 m.sup.2 /g.

REFERENCES:
patent: 2325422 (1943-07-01), Palmer et al.
patent: 2420131 (1947-05-01), Goldblatt et al.
patent: 2444790 (1948-07-01), Rummelsburg
patent: 3281485 (1966-10-01), Blackmore
patent: 3714283 (1973-01-01), Rice et al.

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