Isomerization of hydrofluorocarbon

Details Isomerization of hydrofluorocarbon Isomerization of hydrofluorocarbon

1999-12-22

2001-05-15

Siegel, Alan (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

Reexamination Certificate

active

06232513

ABSTRACT:

FIELD OF THE INVENTION
The subject of the present invention, which relates to the field of fluorinated hydrocarbons, is the isomerization of hydrofluorocarbons (HFC) and, more particularly, that of 1,1,2,2-tetrafluoroethane (F134) into 1,1,1,2-tetrafluoroethane (F134a).
BACKGROUND OF THE INVENTION
F134a is one of the hydrofluorocarbons (HFC) falling within the context of the replacement of the chlorofluorocarbons (CFC) and hydrochlorofluorocarbons (HCFC) which have already been banned or are in the process of being banned because of their harmful effect on the stratospheric ozone layer.
Several ways of obtaining F134a are known, namely:
the fluorination of 1-chloro-2,2,2-tri-fluoroethane (F133a) in gas or liquid phase;
the fluorination of trichloroethylene in liquid phase;
the hydrogenolysis of 1,1-dichloro-1,2,2,2-tetrafluoroethane (F114a) or of 1-chloro-1,2,2,2-tetrafluoroethane (F124);
the isomerization of 1,1,2,2-tetrafluoroethane (F134).
According to the literature, the latter process is carried out using catalysts. Thus, Patents EP 365,296 and JP 03 261731 describe the use of chromium-based catalysts and U.S. Pat. No. 4,902,838 claims a catalyst of the fluorinated alumina type; Patent JP 02 115135 prefers to use a catalyst of the aluminium chlorofluoride type. The use of a catalyst is not always sufficient; thus, U.S. Pat. No. 4,902,838 recommends introducing oxygen into the medium so as to maintain the catalytic activity over time and Patent Application WO 95/15300 recommends introducing a source of chloride ions.
DESCRIPTION OF THE INVENTION
It has now been found that it is possible to isomerize F134 into F134a without the aid of a catalyst, by a simple heat treatment in the presence of hydrogen. This method may also apply to the isomerization of other HFCs, for example to that of 1,1,2-trifluoroethane (F143) into 1,1,1-trifluoroethane (F143a) or to that of 1,2-difluoroethane (F152) into 1,1-difluoroethane (F152a).
The subject of the present invention is therefore a process for the isomerization of a hydrofluorocarbon having a certain thermodynamic stability (HFC 1) into a hydrofluorocarbon of greater thermodynamic stability (HFC 2), characterized in that the hydrofluorocarbon HFC 1 is subjected to a heat treatment in the presence of hydrogen at a temperature above 500° C.
The process according to the invention is advantageously carried out at a temperature of between 500 and 1000° C., preferably between 600 and 750° C.
The pressure of the reaction may be between 0.1 and 50 bar, but it is preferred to work between atmospheric pressure and 20 bar.
The H
2
/HFC 1 molar ratio may range from 1 to 100, but it is generally preferred to work with a molar ratio of between 2 and 20. The flux of reactants (HFC 1 and H
2
) entering the reactor may be diluted with an inert gas, such as helium or nitrogen.
The residence time of the reactants in the hot part of the reactor may vary over wide ranges. It varies inversely with the temperature and is generally between 0.1 and 1000 seconds, preferably between 1 and 300 seconds.
The isomerization may be carried out in an empty reactor, i.e. a reactor which contains no packing but which may, however, be equipped with thermocouples and baffles. The reactor may be made of quartz or metal. In this case, the metal of the material forming the reactor may be chosen from metals such as nickel, iron, titanium, chromium, molybdenum, cobalt and gold, or their alloys. The metal, chosen more particularly for limiting the corrosion or the catalytic phenomena, may form a solid wall or it may be plated onto another metal, as in the case of a reactor gold-plated on its internal surface.


REFERENCES:
patent: 2315871 (1943-04-01), Oberfell et al.
patent: 4902838 (1990-02-01), Manzer et al.
patent: 4950815 (1990-08-01), Moore et al.
patent: 5030372 (1991-07-01), Manogue et al.
patent: 5091600 (1992-02-01), Moore et al.
patent: 365296 (1990-04-01), None
patent: 2-115135 (1990-04-01), None
patent: 3-261731 (1991-11-01), None
patent: WO 95/15300 (1995-06-01), None

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