Isomerization of endo-tetrahydrodicyclopentadiene to a missile f

Details Isomerization of endo-tetrahydrodicyclopentadiene to a missile f Isomerization of endo-tetrahydrodicyclopentadiene to a missile f

1976-09-03

1978-04-25

Lechert, Jr., Stephen J.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

60208, C07C 100

Patent

active

040862844

ABSTRACT:
Endo-tetrahydrodicyclopentadiene is isomerized to its exo-isomer in the presence of aluminum trichloride at a temperature in the range between from about -.degree. C to about 90.degree. C. The mole ratio of AlCl.sub.3 to the tetrahydrodiene is in the range between from about 0.001 to about 0.75. An inert solvent may also be used. The very facile isomerization is essentially quantitative. The exoisomer has utility as a relatively high BTU/gallon, viscosity-lowering difluent for a missile fuel.

REFERENCES:
patent: 3864178 (1975-02-01), Rudy et al.

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