Isomerization of 2-pentenoates to 3-pentenoates

Details Isomerization of 2-pentenoates to 3-pentenoates Isomerization of 2-pentenoates to 3-pentenoates

1987-11-18

1989-10-17

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560220, 560221, 562598, C07C 67333

Patent

active

048748897

ABSTRACT:
3-Pentenoates are prepared by isomerization of 2-pentenoates to 3-pentenoates by a process in which the 2-pentenoate is treaated with from 0.01 to 0.5 mole of cyclic tertiary amine having a pK.sub.a of >6 per mole of 2-pentenoate at from 50.degree. to 250.degree. C. and the 3-pentenoate is distilled off continuously.

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