Isocyanate-functional polymers containing a terminal monosulfide

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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4273882, 4284231, 428441, 428463, 526312, 526214, 526224, 525293, 525301, 525303, 524850, C08K 510, C08F 2602, B32B 1710

Patent

active

043517552

ABSTRACT:
Low molecular weight polydisperse isocyanate-functional acrylic polymers are provided which contain terminal monosulfide groups on at least 10% by number of polymer molecules but are substantially free of toxic monomeric isocyanates.
The polymers are prepared by direct reaction of the monomers, e.g., 2-isocyanatoethyl methacrylate and butyl acrylate, in the presence of a mercaptan chain-transfer agent and a polymerization initiator but in the substantial absence of water and of Lewis-type bases. They can be crosslinked and are useful in a variety of applications such as moisture-curing coating compositions.

REFERENCES:
patent: 2471959 (1949-05-01), Hunt
patent: 2718516 (1955-09-01), Bortnick
patent: 3498943 (1970-03-01), Dannals
patent: 3579482 (1971-05-01), Brotherton
patent: 3632796 (1972-01-01), Holicky

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