Isobutane conversion of naphtha in pretreater desulfurization

Mineral oils: processes and products – Chemical conversion of hydrocarbons – With preliminary treatment of feed

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C01G 2300

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active

039961281

ABSTRACT:
In a hydrocarbon conversion process for the catalytic desulfurization of a hydrocarbon feedstock the process is carried out at a low hydrogen partial pressure to obtain formation of a low sulfur product and conversion to butanes and propane, as desired, wherein the isoC.sub.4
-C.sub.4 ratio is high, the process being carried out in the presence of an active, stable and selective catalyst containing at least one noble metal component incorporated with a crystalline aluminosilicate. A pressure from 100 to below 500 psig is used. The process contemplates simultaneously pretreating reformer feedstock in the presence of a hydrocracking catalyst with controlled hydrocracking thereof. Preferred highly effective catalysts are those containing palladium incorporated with a crystalline aluminosilicate zeolite.

REFERENCES:
patent: 3105811 (1963-10-01), Engel
patent: 3291723 (1966-12-01), Blue
patent: 3314878 (1967-04-01), Kozlowski
patent: 3409539 (1968-11-01), Paterson
patent: 3497448 (1970-02-01), Hamner et al.
patent: 3884797 (1975-05-01), Alley, Jr. et al.

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