Compositions – Electrically conductive or emissive compositions – Metal compound containing
Patent
1983-11-30
1985-07-02
Barr, Josephine L.
Compositions
Electrically conductive or emissive compositions
Metal compound containing
526285, 524174, 528488, 429213, H01B 106
Patent
active
045267081
ABSTRACT:
Conjugated backbone polymers (e.g., polyacetylene), especially formed into a battery electrode, are contacted with a compound MR where M is an alkali metal and R is alkyl of 1-12 carbons, phenyl or alkylphenyl of 7-12 carbons. The method is particularly suited to treatment of battery electrodes to avoid a high initial internal resistance.
REFERENCES:
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patent: 4321114 (1982-03-01), MacDiarmid et al.
M. B. Dines, Mat. Res. Bull., vol. 10, pp. 287-292, (1975), "Lithium Intercalation via n-Butyllithium of the Layered Transition Metal Dichalcogenides".
A. A. Morton et al., Journal of Organic Chemistry, vol. 23, p. 1626, "Metalation of Cumene" (1958).
M. S. Whittingham et al., J. Electro-Chem. Sci and Technical., vol. 124, pp. 1387-1388 (1979).
J. of Polymer Science, Polymer Chemical Edition, vol. 12, p. 11 (1974).
Synthetic Metals, vol. 1 (1979/1980), pp. 101-118, A. G. MacDiarmid et al., "Organic Metals and Semiconductors: Chemistry of Polyacetylene, (CH).sub.x, and Its Derivatives".
Journal De Physique, Colloque C3, Tome 44, 06-1983, "Chemical N Doping of Polyacetylene", B. Francois et al., pp. C3 21-C3 28.
Elsenbaumer Ronald L.
Miller Granville G.
Toth James E.
Allied Corporation
Barr Josephine L.
Doernberg Alan M.
Fuchs Gerhard H,.
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