Iron/silicon-based catalyst exhibiting high selectivity to C.sub

Catalyst – solid sorbent – or support therefor: product or process – Irradiation by – or application of – electrical – magnetic or...

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2041571H, 423346, 423439, 502 53, 502178, 502258, 518719, 518720, B01J 3734, B01J 2122, C01B 3136, C07C 104

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044684746

ABSTRACT:
Finely divided, hydrogen-activated catalyst compositions comprising iron, silicon and carbon or iron and silicon that selectively convert gaseous mixtures of CO and H.sub.2, at a temperature of about 150.degree.-450.degree. C. and at pressures of about 10-2000 kPa, into reaction mixture containing at least about 75% C.sub.2 -C.sub.6 alkenes and no more than about 25% of CH.sub.4 and undesirable CO.sub.2 by-products are disclosed. A wide range of iron/silicon-based catalyst compositions are conveniently prepared by laser pyrolysis and hydrogen-pretreatment and readily reactivated with hydrogen at elevated temperatures.

REFERENCES:
patent: 3755541 (1973-08-01), Strepkoff
patent: 3979500 (1976-09-01), Sheppard et al.
"Solid-Phase Synthesis of Some Transition Metal Silicides" by B. K. Voronov, et al., INSPEC-DIN s5808-0217-c; pp. 962-965, Plenum Publishing Co., New York, 1975.

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