Catalyst – solid sorbent – or support therefor: product or process – Irradiation by – or application of – electrical – magnetic or...
Patent
1983-05-16
1984-08-28
Konopka, P. E.
Catalyst, solid sorbent, or support therefor: product or process
Irradiation by, or application of, electrical, magnetic or...
2041571H, 423346, 423439, 502 53, 502178, 502258, 518719, 518720, B01J 3734, B01J 2122, C01B 3136, C07C 104
Patent
active
044684746
ABSTRACT:
Finely divided, hydrogen-activated catalyst compositions comprising iron, silicon and carbon or iron and silicon that selectively convert gaseous mixtures of CO and H.sub.2, at a temperature of about 150.degree.-450.degree. C. and at pressures of about 10-2000 kPa, into reaction mixture containing at least about 75% C.sub.2 -C.sub.6 alkenes and no more than about 25% of CH.sub.4 and undesirable CO.sub.2 by-products are disclosed. A wide range of iron/silicon-based catalyst compositions are conveniently prepared by laser pyrolysis and hydrogen-pretreatment and readily reactivated with hydrogen at elevated temperatures.
REFERENCES:
patent: 3755541 (1973-08-01), Strepkoff
patent: 3979500 (1976-09-01), Sheppard et al.
"Solid-Phase Synthesis of Some Transition Metal Silicides" by B. K. Voronov, et al., INSPEC-DIN s5808-0217-c; pp. 962-965, Plenum Publishing Co., New York, 1975.
Gupta Arunava
Yardley James T.
Allied Corporation
Fuchs Gerhard H,.
Hampilos Gus T.
Hoffman Thomas D.
Konopka P. E.
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