Iridium carbonyl complexes

Details Iridium carbonyl complexes Iridium carbonyl complexes

1974-07-29

1977-06-14

Thomas, Earl C.

Chemistry of inorganic compounds

Carbon or compound thereof

Oxygen containing

423417, C01G 104

Patent

active

040297489

ABSTRACT:
The complexes [Ir(CO).sub.3 I], [HIr(CO).sub.3 I.sub.2 ], [HIr(CO).sub.2 I.sub.2 (H.sub.2 O)], [RIr(CO).sub.2 I.sub.2 ], [(RCO)Ir(CO).sub.2 I.sub.2 ] where R is an alkyl radical, are described. Processes for preparing the aforesaid complexes are described and in addition a new process for preparation of [Ir(CO).sub.3 I.sub.3 ] is described.

REFERENCES:
patent: 3816337 (1974-06-01), Usami et al.
patent: 3855396 (1974-12-01), Kniese et al.
L. Malatesta et al., J. Chemical Society, 961-965, (1964).
D. Forster, Inorganic Chemistry, 11, 473-475, (1972).

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