Stoves and furnaces – Heat accumulator structures
Patent
1985-03-28
1986-08-19
Scott, Samuel
Stoves and furnaces
Heat accumulator structures
126452, 502155, 502152, B01J 3108
Patent
active
046063269
ABSTRACT:
Novel catalyst for the photochemical conversion and storage of radiant energy through the conversion of strained cyclic non-conjugated carbon containing compounds to their corresponding conjugated forms comprises ionically bonding a transition metal complex having a square planar geometry and multiple sites of coordination with an anion-exchange resin. A method is provided for the preparation of the novel catalyst and comprises forming an acid salt derivative of the transition metal complex and mixing it together with an anion-exchange resin. A process wherein the novel catalyst is added to a strained cyclic non-conjugated carbon containing compound resulting in the release of heat energy through the conversion of the non-conjugated carbon containing compound to its conjugated form. A process and sealed container means wherein the non-conjugated carbon containing compound and the catalyst are in compartments and are separated until heat energy is required. The means of separation is then broken and the non-conjugated carbon containing compound is converted to the conjugated form with the release of heat energy. A process and apparatus wherein the conjugated carbon containing compound is exposed to radiant energy and is converted to the non-conjugated form. The non-conjugated form is then combined with the catalyst described hereinabove, converting the non-conjugated form to the conjugated form and resulting in the release of heat energy which is collected.
REFERENCES:
patent: 2950237 (1960-08-01), Sharp
patent: 3542032 (1970-11-01), Spencer, Jr.
patent: 4004571 (1977-01-01), Schwerzel et al.
patent: 4004572 (1977-01-01), Nathan et al.
patent: 4004573 (1977-01-01), Frieling et al.
patent: 4080953 (1978-03-01), Mitchell et al.
patent: 4105014 (1978-08-01), Schwerzel
patent: 4298502 (1981-11-01), Carlson
patent: 4378305 (1983-03-01), Carlson
patent: 4394858 (1983-07-01), Giordano et al.
patent: 4424805 (1984-01-01), Neary
patent: 4446041 (1984-05-01), Neary
patent: 4449516 (1984-05-01), Kitao et al.
patent: 4504371 (1985-03-01), Cirjak
patent: 4507185 (1985-03-01), King, Jr. et al.
J. Manassen, "Catalysis of a Symmetry Restricted Reaction by Transition Metal Complexes. The Importance of the Ligand", Journal of Catalysis (vol. 18, 38-45, 1970).
L. D. Rollman, "Porous, Polymer-Bonded Metalloporphyrins", Journal of the American Chemical Society, (vol. 97, 2132-2136, 1973).
B. B. King et al., "Polymer-Anchored Cobalt Tetraarylporphyrin Catalysts of Quadricyclane to Norbornadiene", Journal of Organic Chemistry, (vol. 44, No. 3, 385-391, 1979).
K. Maruyama et al., "Exploitation of Solar Energy Storage Systems. Valence Isomerization Between Norbornadiene and Quadricyclane Derivatives", Journal of Organic Chemistry (vol. 46, 5294-5300, 1981).
Giordano, Jr. Paul J.
Smierciak Richard C.
Curatolo Joseph G.
Evans Larry W.
McKinney Sue E.
Odar H. A.
Scott Samuel
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