Ionic hydrogenolysis of Binor-S for use as a high energy fuel

Details Ionic hydrogenolysis of Binor-S for use as a high energy fuel Ionic hydrogenolysis of Binor-S for use as a high energy fuel

1975-05-16

1977-07-05

Engle, Samuel W.

Explosive and thermic compositions or charges

High energy fuel compounds

1491094, 260666PY, 260690, 252477Q, C06B 2300, B01J 3500, C07C 100

Patent

active

040337995

ABSTRACT:
Ionic hydrogenolysis of Binor-S, a C.sub.14 heptacyclic saturated hydrocarbon, yields a low melting point product containing predominantly hexacyclics and lesser amounts of pentacyclics. Hydrogenolysis occurs at about 50.degree.-200.degree. C and at about 100-10,000 p.s.i.g. in the presence of a palladium-on-carbon catalyst, palladium-on-alumina or Raney nickel and is promoted by a hydrogen halide or its equivalent. Resulting product has utility as a high energy fuel.

REFERENCES:
patent: 3258502 (1966-06-01), Cannell
patent: 3265749 (1966-08-01), Cannell
patent: 3282663 (1966-11-01), Muller
patent: 3326992 (1967-06-01), Muller
patent: 3326993 (1967-06-01), Bastian
patent: 3544485 (1970-12-01), Taira
Schrauzer, et al., Journal of the American Chemical Society, 88:21, Nov. 5, 1966, pp. 4890-4894.

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