Ion-sensitive FET sensor

Chemistry: electrical and wave energy – Apparatus – Electrolytic

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

204416, 357 25, G01N 2730

Patent

active

048161187

ABSTRACT:
An ion-sensitive FET sensor has a MOSFET gate isolating membrane whose surface is covered by an ion-sensitive layer. A redox layer having a redox function is provided between the isolating membrane and the ion-sensitive layer to improve operating stability and speed of response. An electrically conductive layer or a combination of a thin metal film and an electrically conductive layer is provided between the isolating membrane and the redox layer to further improve operating stability, the adhesion of the layers and the durability of the sensor. Also disclosed are optimum materials for use as an ion carrier employed in the ion-sensitive layer.

REFERENCES:
patent: 3926764 (1975-12-01), Ruzicka et al.
patent: 3932233 (1976-01-01), Ruzicka et al.
patent: 3957612 (1976-05-01), Niedrach et al.
patent: 3957613 (1976-05-01), Macur
patent: 4052285 (1977-10-01), Dobson
patent: 4115209 (1978-09-01), Freiser et al.
patent: 4198851 (1980-04-01), Janata
patent: 4214968 (1980-07-01), Battaglia et al.
patent: 4280889 (1981-07-01), Szonntagh
patent: 4282099 (1981-08-01), Chang et al.
patent: 4305802 (1981-12-01), Koshiishi
patent: 4454007 (1984-06-01), Pace
patent: 4512870 (1985-04-01), Kohara et al.
patent: 4549951 (1985-10-01), Knudson et al.
patent: 4561962 (1985-12-01), Kankare
patent: 4563263 (1986-01-01), Oyama et al.
patent: 4615954 (1986-10-01), Solomon et al.
patent: 4632732 (1986-12-01), Fog et al.
Tamura et al., "Coated Wire Sodium- and Potassium-Electrodes Based on Bis(crown ether) Compounds", Analytical Chemistry, vol. 54, No. 7, Jun. 1982, pp. 1224-1227.
Wuthier et al., "Tin Organic Compounds as Neutral Carriers for Anion Selective Electrodes", Analytical Chemistry, vol. 56, No. 3, Mar. 1984, pp. 535-538.
Norov et al., "Calcium-Selective Electrode Without an Internal Reference Solution", Journal of Analytical Chemistry, vol. 34, No. 8, Part 1, Aug. 1979, pp. 1159-1162.
Oyama et al., "Hydrogen Ion Selective Microelectrode Prepared By Modifying An Electrode With Polymers", Analytical Chemistry 1987, vol. 59, pp. 258-262.
Oyama, "Ion Selective Microelectrode Prepared By Modifying An Electrode With Polymers", International Electrical Symposium, Schaumberg, Illinois, May 27-29 (1987), pp. 122-125.
Oyama et al., "A New Type of Ion-Selective Microelectrodes Using Electropolymerize Thin Films", j-4 Bioelectroanalytical Chemistry Symposium, Honolulu, Hawaii, Oct. 18-23, 1987.
Oyama et al., "Ion Selective Electrode Prepared By Modifying an Electrode With Polymers", Tokyo Seminar on Macromolecular Complexes, Tokyo Univ., Oct. 14-17, 1987.
Moss et al., "Potassium Ion-Sensitive Field Effect Transistor," Analytical Chemistry, vol. 47, No. 13, Nov. 1975.
Cattrall et al., "Potassium Ion Responsive Coated Wire Electrode Based on Valinomycin," Analytical Chemistry, vol. 46, No. 14, Dec. 1974.
Ohnuki et al., "Permselectivity of Films Prepared by Electrochemical Oxidation of Phenol and Amino-Aromatic Compounds," J. Electroanal. Chem., 158 (1983) 55-67.
Heinemann et al., "Polymer Film Chemically Modified Electrode as a Potentiometric Sensor," Anal. Chem. 1980, 52, 345-346.
Cheek et al., "pH Response of Platinum and Vitreous Carbon Electrodes Modified by Electropolymerized Films," Anal. Chem. 1983, 55, 380-381.
Rubinstein, "Voltammetric pH measurements with Surface-Modified Electrodes and a Voltammetric Internal Reference," Anal. Chem. 1984, 56, 1135-1137.
Oyama et al., "Facile Attachment of Transition Metal Complexes to Graphite Electrodes Coated With Polymeric Ligands, Observation and Control of Metal-Ligand Coordination among Reactants Confined to Electrode Surfaces," Journal of the American Chemical Society, 101, 739 (1979).
Oyama et al., "Electrostatic Binding of Metal Complexes to Electrode Surfaces Coated with Highly Charged Polymeric Films," J. Electrochem. Soc., vol. 127, No. 1, Jan. 1980, pp. 247-250.
Oyama et al., "Catalysis of Electrode Processes by Multiply-Charged Metal Complexes Electrostatically Bound to Polyelectrolyte Coatings on Graphite Electrodes, and the Use of Polymer-Coated Rotating Disk Electrodes in Diagnosing Kinetic and Conduction Mechanisms," Anal. Chem. 1980, 52, 1192-1198.
Snell et al., "Surface Modified Electrodes," Chem. Soc. Rev. 1979, 8, 259-282.
Faulkner, "Chemical Microstructures on Electrodes," Chem. Eng. News, 1984, 27, pp. 28-45.
Oyama et al., "Electrochemical Properties of Electropolymerized Poly (1-pyrenamine) Films," Bull. Chem. Soc. Jpn., 1986, 59, 2071-2080.
Schulthess et al., "A Hydrogen-Ion Selective Liquid-Membrane Electrode based on Tri-n-Dodecylamine as Neutral Carrier," Analytica Chimica Acta, 131, (1981) 111-116.
Electrochemical Detectors Fundamental Aspects and Analytical Applications, T. H. Ryan, p. 7.
Organic Analysis Using Ion-Selective Electrodes, vol. 2, T. S. Ma, pp. 60 and 62.
Oyama et al., "Electrochemical Properties of Electropolymerized Poly (1-pyrenamine) Films," The Chemical Society of Japan, Jul. 1986.
T. H. Ryan, "Electrochemical Detectors", p. 7.
Ma et al., "Oranic Analysis Using Ion-Sensitive Electrodes", vol. 2, pp. 60 & 62.
Ammann, "Ion-Selective Microelectrodes", Principles, Design & Application, pp. 5-7, 66 & 100.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Ion-sensitive FET sensor does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Ion-sensitive FET sensor, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Ion-sensitive FET sensor will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1657186

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.