Ion mobility spectrometer system with improved specificity

Radiant energy – Ionic separation or analysis – Ion beam pulsing means with detector synchronizing means

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250282, 422 98, B01D 5944, G01N 2766

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active

045516243

ABSTRACT:
An ion mobility spectrometer system with improved specificity. The ion mobility spectrometer has a reaction chamber and a drift chamber, an ionization source disposed in the reaction chamber, an injection grid separating said reaction and drift chambers, a collector electrode disposed in the drift chamber and a sample input injecting the sample and carrier into the reaction chamber.
A source injects acetone and/or carbon tetrachloride as reagents into the carrier gas prior to entering the sample input. The acetone reactant forms a dimer ion in the positive ion spectrum which impedes the clustering of water and provides a narrow fixed peak in the ion spectrum which serves as a reference point in the ion spectrum for the algorithm used in the electronic control unit generating an output characteristic of the sample. The carbon tetrachloride reactant forms a (H.sub.2 O).sub.n Cl.sup.- ion which provides a reference in the negative ion spectrum for the algorithm used in the electronic control unit. The acetone and carbon tetrachloride reactants both rendering the ion mobility spectrometer more specific for detection and identification.

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Carr, Comparison of the Negative Reactant Ions Formed in the Plasma Chromatograph by Nitrogen, Air, Sulfur Hexafluoride as the Drift Gas with Air as the Carrier Gas, Anal. Chem., vol. 51, No. 6, May 1979.

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