Ion exchange polymers and method for making

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing

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521 25, 521 27, 521 31, 525154, 5253302, 525383, B01J 3918, C08F 828, C08J 522, C08L 2326

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active

053711106

ABSTRACT:
An ion exchange polymer comprised of an alkali metal or alkaline earth metal salt of a poly(carboxylic acid) in a poly(vinyl acetal) matrix is described. The polymer is made by treating a mixture made of poly(vinyl alcohol) and poly(acrylic acid) with a suitable aldehyde and an acid catalyst to cause acetalization with some cross-linking. The material is then subjected to an alkaline aqueous solution of an alkali metal salt or an alkali earth metal salt. All of the film forming and cross-linking steps can be carried out simultaneously, if desired.

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patent: 4221872 (1980-09-01), Lydiate
patent: 4298698 (1981-11-01), Kawase
patent: 4357402 (1982-11-01), Sheibley et al.
patent: 4377481 (1983-03-01), Jakabhazy
Philipp et al, Three Methods for In Situ Cross-Linking of Polyvinyl Alcohol Films for Application as Ion-Conducting Membranes in Potassium Hydroxide Electrolyte, Apr. 1979, pp. 3-4, NASA Technical Paper 1407.
Philipp et al, New Ion Exchange Membranes, Oct. 5-10, 1980, pp. 1 and 7; NASA Technical Memorandum 81670.
Philipp et al, Kinetics of Copper Ion Absorption by Cross-Linked Calcium Polyacrylate Membranes Feb. 1983, p. 2, NASA Technical Memorandum 83052.
Philipp et al, Ion Exchange Selectivity for Cross-Linked Polyacrylic Acid, Sep. 1983, NASA Technical Memorandum 83427.

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