Ion-detecting sensors comprising plasticizer-free copolymers

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Means for analyzing liquid or solid sample

Reexamination Certificate

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C204S416000, C204S418000, C205S781500, C422S051000, C422S082010, C422S082020, C422S082050, C422S082060, C422S082070, C422S082080, C422S082090, C422S082110, C436S073000, C436S074000, C436S079000, C436S080000, C436S081000, C436S082000, C436S083000, C436S084000, C436S149000, C436S150000, C436S151000, C436S169000, C436S172000

Reexamination Certificate

active

10856665

ABSTRACT:
Plasticizer-free ion-detecting sensors for detecting a target ion in a sample are provided. The sensor comprises a plasticizer-free copolymer comprised of polymerized units of methacrylate monomers and a polymerizable ion exchanger, wherein the methacrylated monomers have pendent alkyl groups of different length and wherein the functionalized ion-exchanger is grafted into the copolymer through covalent linkages. The ion exchanger comprises a C-derivative of a halogenated closo-dodecacarborane anion having a polymerizable moiety. Sensors of this invention include carrier-based ion-selective electrodes or optodes such as thin film ion-specific optodes, particle-based optodes, or bulk optodes.

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