Ion beam deposition or etching re rubber-metal adhesion

Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...

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428469, 428677, 204192C, 156124, 152359, B32B 1506

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active

044461976

ABSTRACT:
Metal to rubber adhesion is improved by metal substrates having a coating thereon such as brass, copper, and the like. The coating is applied by an ion beam sputter deposition or, in the alternative, such a coating is partially removed through ion beam etching. The present invention is particularly useful in tire cord construction, metal reinforced belts and hoses, and the like, since articles made therefrom have superior and unexpected moisture aged rubber-to-metal adhesion properties.

REFERENCES:
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patent: 4101402 (1978-07-01), Vossen, Jr. et al.
patent: 4211824 (1980-07-01), Yoshida
patent: 4218517 (1980-08-01), Van Ooij
Michael Mirtich, Adherence of Ion Beam Sputtered Deposited Metal Films on H-13 Steel, NASA Lewis Research Center, 1980, pp. 14-17.
C. Weissmantel et al., Surface Science, 86, 1979, pp. 207-210.
W. Hudson et al., NASA Techn. Mem. X-73598, Lewis Research Center, Feb. 14-16, 1977, 6th Ann. Symp. Appl. Vac. Sci. Tech. pp. 1-3.
J. S. Sovey, J. Vac. Sci. Techn. 16, No. 2, Mar.-Apr., 1979, pp. 813-814.
S. M. Kane et al., J. Vac. Sci. Tech. 16 (2) Mar./Apr. 1979, pp. 171-172.
"Advances in Low-Energy Ion Beam Technology," W. Laznovsky, Research and Development, Aug. 1975, pp. 47-55.
"Ion Beam Techniques for Thin and Thick Film Deposition," C. Weissmantel, H. Erler, and G. Reisse, Surface Science 86 (1979), pp. 207-210.
"Ion Beam Texturing," by Wayne Hudson, Published in Journal of Society Technology, vol. 14, No. 1, Jan. and Feb., 1977, pp. 286-287.
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"Ion Beam Sputtering of Fluoropolymers," by Sovey, published in Journal of Vacuum Science and Technology, Mar.-Apr, 1979.
"Characteristics of Ion-Beam-Sputtered Thin Films" by Kane and Ahn of IBM, published in the Journal of Vacuum Science and Technology, Mar.-Apr., 1979, pp. 171-172.

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