Intervulcanized elastomer blends

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525192, 525194, 525195, 525232, 525912, 525215, 525233, 524525, C08L 700, C08L 900, C08L 1100, C08L 1300, C08L 2322

Patent

active

054730171

ABSTRACT:
Intervulcanized compositions having improved curing efficiency are prepared by the free radical curing of a mixture of an ethylenically unsaturated diolefin polymer such as natural or synthetic rubber and a saturated or low unsaturation polymer such as an isobutylene/para-methylstyrene copolymer which contains functional groups pendant to the polymer chain. These functional groups contain an olefinic or vinyl double bond positioned alpha, beta to a substituent group which activates the double bond towards free radical addition reactions with the diolefin polymer. Preferred functionality includes benzylic ester functionality represented by the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from hydrogen or C.sub.1 to C.sub.6 alkyl, and R.sub.4 is selected from hydrogen, C.sub.1 to C.sub.28 alkyl, aryl or C.sub.2 to C.sub.28 alkenyl.

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