Interpolymer cures of blends comprising halogenated isoolefin/pa

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525209, 525232, 525235, C08L 900, C08L 1502

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active

056566948

ABSTRACT:
Vulcanizable blends containing a halogenated copolymer of a C.sub.4 -C.sub.7 isomonoolefin and para-alkylstyrene mixed with one or more olefinically unsaturated elastomeric polymers are disclosed. Cure is preferably effected using zinc stearate as a curative at levels below about 3.0 phr which gives rise to vulcanizates having selective interpolymer addition of benzylic halogen present in the halogenated copolymer to the double bond of the unsaturated polymer with no significant self curing of the halogenated polymer taking place.

REFERENCES:
patent: 5063268 (1991-11-01), Young
patent: 5376438 (1994-12-01), Costemalle
patent: 5385459 (1995-01-01), Graves
patent: 5397837 (1995-03-01), Arjunan
"Exxon Bromo XP-50 Rubber Compounding" Exxon Chemical Company Brochure, May, 1992.
"Achieving Efficient Co-Cure", Gardner et al., Nov. 3-6, 1992, Presented at a meeting of the Rudder Div. of ACS.
Frechet "Electrophilic Addition of Brominated Poly(isobutylene-4 methyl styrene) to Olefines Catalyzed by Zinc Salts" Rubber Chemistry and Technology 66(1) Mar. 1993 pp. 98-108.
Bielski "Electrophilic Aromatic Substitution in the Curing of Brominated Poly(isobutylene 4 methylstyrene" Journal of Polymer Science: Polymer Chemistry 31(3) Mar. 1993 pp. 755-762.

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