Internally doped high chloride {100} tabular grain emulsions

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430604, 430605, G03C 1035, G03C 108

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active

054570212

ABSTRACT:
A process is disclosed of preparing a radiation sensitive silver halide emulsion comprising reacting silver and halide ions in a dispersing medium in the presence of a metal hexacoordination or tetracoordination complex having at least one organic ligand and at least half of the metal coordination sites occupied by halide or pseudohalide ligands. The metal forming the complex is chosen from periods 4, 5 and 6 and groups 3 to 14 inclusive of the periodic table of elements. The incorporation of the transition metal ion dopant and at least one organic ligand into the cubic crystal lattice of the silver halide grains can be used to improve photographic performance.

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