Internal stabilization of polycarbonate resins by two stage radi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522163, 522907, 2041579, 20415788, 528125, 528196, 528204, C08J 328, C08G 6112, C08G 6346

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active

047497262

ABSTRACT:
A new polycarbonate copolymer resin is formed by internal generation of stabilizers bound to the polymer chain. Irradiation of a solid piece or a deoxygenated solution of the resin at a first frequency below 300 nm generates 2 to 8 mol percent of phenyl salicylate groups which are rearranged to dihydroxybenzophenone groups by irradiating the resin under oxygen excluding conditions at a second frequency from 300 to 320 nm.

REFERENCES:
Gupta et al., "Macromolecules" vol. 13, No. 2, Mar.-Apr. 1980, American Chemical Society, pp. 262-267.

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