Internal hydroformylation of acrolein acetals

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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568451, 568455, 568599, 568600, 568882, 568909, 549374, C07D31710, C07D31904, C07C 4300

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active

043749992

ABSTRACT:
Acrolein acetals are selectively hydroformylated on the unsaturated carbon atom adjacent to the carbon bearing two ether groups in the presence of a supported rhodium-cobalt bimetallic cluster. The resulting internally hydroformylated product is useful as a precursor of methacrylic acid.

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