Intermediates for preparing optically active carboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549455, 549454, 549453, 549452, 549450, 549448, 549436, 549429, C07D31712, C07D31744, C07D31718, C07D31726

Patent

active

048619035

ABSTRACT:
A process is described for preparing optically active alpha-arylalkanoic acids consisting of rearranging an optically active ketal of formula ##STR1## in which the substituents have the meaning given in the description of the invention.

REFERENCES:
patent: 4560777 (1985-12-01), Giordano et al.
patent: 4605758 (1986-08-01), Schloemer
Ulrich et al., C.A., 115,561j, (1967).
Journal of Organic Chemistry, vol. 43, No. 25, Dec. 8, 1978, pp. 4689, 4876-4878.
Journal of the Chemical Society, Perkin Transactions I, Organic and Bio-Organic Chemistry, 1982, pp. 2575-2580.
Angewandte Chemie, vol. 23, 1984, pp. 413-419.
Asymmetric Synthesis, vol. 4, 1984, The Chrial Carbon Pool and Chiral Sulfur, Nitrogen, Phosphorus, and Silicon Centers, pp. 10-57.

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