Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles
Patent
1983-08-29
1986-07-01
Chan, Nicky
Organic compounds -- part of the class 532-570 series
Organic compounds
Nitriles
260 53F, 260544F, 260543H, 260543R, 560150, 560153, 562605, 564209, 568 31, 568 41, 558437, C07C12116, C07C14308
Patent
active
045979138
ABSTRACT:
A novel fluorinated cation exchange membrane containing carboxylic acid groups and sulfonic acid groups, both in the form of a specific pendant structure, the carboxylic acid groups being at least 20% on one surface of the membrane and gradually decreasing toward the innerside of the membrane, which membrane is useful in electrolysis of an aqueous alkali metal halide solution with advantageously stable performance for a long term under more severe operational conditions than those conventionally used. The membrane can be prepared from a novel copolymer of a fluorinated olefin with a novel sulfur containing fluorinated vinylether of the formula: ##STR1## wherein k is 0 or 1, l is an integer of 3 to 5, Z is --S-- or --SO.sub.2 -- and R is C.sub.1 -C.sub.10 alkyl, an aryl, C.sub.1 -C.sub.10 perfluoroalkyl.
REFERENCES:
patent: 3062879 (1962-11-01), Drysdale
patent: 3437686 (1969-04-01), Slagel et al.
patent: 4151053 (1979-04-01), Seko et al.
patent: 4176215 (1979-11-01), Molnar et al.
Ebisawa Mikio
Hane Toshioki
Kimoto Kyoji
Miyauchi Hirotsugu
Ohmura Jukichi
Asahi Kasei Kogyo Kabushiki Kaisha
Chan Nicky
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