Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1985-03-11
1986-07-01
Chan, Nicky
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
549416, 549411, 549408, 260395, 556449, 560109, 568766, 568650, 568646, 568640, 568592, C07C 69773, C07C 3919
Patent
active
045981604
ABSTRACT:
A catalytic synthesis of chromans in racemic or optically active forms, including intermediates thereto; the synthesis employs an asymmetric palladium (II) catalyzed oxidative cyclization of a 2-homoallylphenol and provides intermediates useful in making chromans, especially vitamin E in racemic or optically active forms.
REFERENCES:
patent: 2270634 (1942-01-01), Isler
patent: 3354181 (1967-11-01), Gloor et al.
patent: 3646222 (1972-02-01), Kawamatsu et al.
Chan Nicky
Coburn Patricia A.
Gould George M.
Hoffmann-La Roche Inc.
Saxe Jon S.
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