Interfacial crud removal system for solvent extraction and...

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

Reexamination Certificate

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C210S511000, C210S525000, C210S634000, C210S803000, C266S101000

Reexamination Certificate

active

06500232

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to equipment and methods for the removal of crud formed at the interface between aqueous and organic phases in solvent extraction processes for the recovery of metal from metal ores.
BACKGROUND OF THE INVENTION
A major problem in solvent extraction plants used for the solvent extraction of metal values from aqueous solutions obtained from the leaching of metal ores is the formation of interfacial sludge, commonly referred to as gunk or crud. Excess crud formation can lead to a number of problems, requiring the regular removal of the crud from the settling tanks. Known methods for the removal of crud are almost all labor intensive, i. e. involve the physical removal of the crud by an operator.
Since the crud is at least about 50% organic, it is economically important to recover most if not all of the entrained organic phase.
The present invention relates to novel methods and equipment that function effectively to remove the crud without the need for constant operator monitoring.
SUMMARY OF THE INVENTION
The process of the invention is carried out by means of at least one rotating auger (conveyor screw) positioned at the interface between the aqueous and organic phases in an SX settler used in the solvent extraction process for recovering metal from metal ores, e.g. copper ores, nickel ores, zinc ores, uranium ores, etc. The rotating auger(s) are run continuously or intermittently at timed intervals to remove crud from the liquids interface. The SX settlers are sometimes referred to as mixer-settlers.


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patent: 3989467 (1976-11-01), Paige
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Jenkins, et al., “Utilization of Surfactants to Separate Solids From Organic in SX”Reagents for Better Metallurgy, Society for Mining, Metallurgy and Exploration, Inc., Chapter 36, (1994), pp. 349-357.
Ritcey, “Crud in Solvent Extraction Processing -A Review of Causes and Treatment”Hydrometallurgy, vol. 5, Elsevier Scientific Publishing Co., Amsterdam, (1980), pp. 97-107.
Kordosky, “Copper Solvent Extraction: The State of the Art”, The Journal of the Minerals, Metals & Materials Society, vol. 44, No. 5, (May, 1992), pp. 40-45.
Virnig, et al., “Crud Formation: Field Studies and Fundamental Studies”, Hydrometallurgy of Copper, vol. IV, The Minerals, Metals & Materials Society, (1999), pp. 291-304.
Kordosky, et al., “Pilot Plant Studies on The Relationship Between Copper Solvent Extraction Reagents and Crud Formation”, Society For Mining, Metallurgy, and Exploration, Inc., (Paper presented at SME Annual Meeting, Phoenix, Arizona, Mar. 11-14, 1996), pp. 1-5.

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