Interfacial cross-linking of latex films

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 296RW, 260 296WB, 260 296H, 525902, C08L 5104

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042934761

ABSTRACT:
Cross-linked, synthetic polymer compositions comprising an aqueous polymer dispersion of (1) heterogeneous polymer particles having a high concentration of reactive groups such as an activated halogen on their surface and (2) a water-soluble coreactive component bearing a plurality of reactive groups coreactive with the reactive groups of the heterogeneous polymer particle, e.g., ##STR1## are useful for preparing strong films or coatings. For example, a polymer composition consisting of an aqueous colloidal dispersion of heterogeneous polymer particles having a shell layer derived from a reactive monomer such as vinylbenzyl chloride and a coreactive component of triethylenetetraamine can be applied to a suitable substrate and cross-linked to form a strong, water-resistant film.

REFERENCES:
patent: 3215647 (1965-11-01), Dunn
patent: 3457209 (1969-07-01), Mikofalvy
patent: 3745196 (1973-07-01), Lane
patent: 3912682 (1975-10-01), Tucker
patent: 4082884 (1978-04-01), De Long
patent: 4098746 (1978-07-01), Becker
patent: 4126595 (1978-11-01), Martorano

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