Intercalation compound of a graphite with a thiazyl salt, a proc

Chemistry of inorganic compounds – Nitrogen or compound thereof – Carbon containing

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252502, 252506, C01C 320

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043691706

ABSTRACT:
A novel intercalation compound of a graphite with a thiazyl salt represented by the formula Z.S.sub.4 N.sub.4.2SbCl.sub.5 wherein Z stands for C.sub.24, pyrolytic carbon or pyrolytic graphite is prepared by reacting a graphite material with trithiazyl trichloride and antimony trichloride in the presence of a non-polar solvent. The graphite intercalation compound thus obtained has not only an excellent stability to humidity or moisture but also a high electrical conductivity. The novel intercalation compound according to the present invention may be practically used as a novel electrically conductive material and a catalyst of organic reactions.

REFERENCES:
T. E. Thompson, E. R. Falardeau and L. R. Hanlon, Carbon, vol. 15, pp. 39-43, (1977).

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