Integrated process using non-stoichiometric sulfides or oxides o

Specialized metallurgical processes – compositions for use therei – Processes – Electrothermic processes

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75 20R, 75 66, 75 67R, 75 69, 75 71, 75 72, 75 77, 75 86, 423414, 423560, 423561A, 423567A, 423641, 423657, 585500, 585534, 585638, 585700, 585733, C21B 1500, C22B 502, C22B 2610

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044419236

ABSTRACT:
Disclosed is a combinative integrated chemical process using inorganic reactants and yielding, if desired, organic products. The process involves first the production of elemental potassium by the thermal or thermal-reduced pressure decomposition of potassium oxide or potassium sulfide and distillation of the potassium. This elemental potassium is then used to reduce ores or ore concentrates of copper, zinc, lead, magnesium, cadmium, iron, arsenic, antimony or silver to yield one or more of these less active metals in elemental form. Process potassium can also be used to produce hydrogen by reaction with water or potassium hydroxide. This hydrogen is reacted with potassium to produce potassium hydride. Heating the latter with carbon produces potassium acetylide which forms acetylene when treated with water. Acetylene is hydrogenated to ethene or ethane with process hydrogen. Using Wurtz-Fittig reaction conditions, the ethane can be upgraded to a mixture of hydrocarbons boiling in the fuel range.

REFERENCES:
patent: 1034320 (1928-07-01), Specketer
patent: 1872611 (1932-08-01), Thurm
patent: 2028390 (1936-01-01), Hanson
patent: 2852363 (1958-09-01), Adams
patent: 3938988 (1976-02-01), Othmer
Mellor, "A Comprehensive Treatise on Inorganic and Theoretical Chemistry", 1922, pp. 445-451.
"Comprehensive Inorganic Chemistry", Pergamon Press, 1973, pp. 371-373.

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