Integrated process for producing carbonylation acetic acid,...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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Reexamination Certificate

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07906680

ABSTRACT:
The present invention is directed to using methyl acetate from a vinyl acetate-based or a vinyl- or ethylene-alcohol based polymer or copolymer process directly for use in a methanol carbonylation production process to produce acetic acid, acetic anhydride, or a coproduction of each. Methyl acetate is a by-product of commercial polyvinyl-alcohol or alkene vinyl alcohol copolymer-based processes. Generally, this material is processed to recover methanol and acetic acid. Discussed herein is a cost-saving scheme to by-pass the methyl acetate processing at production or plant facilities and utilize the methyl acetate in an integrated methanol carbonylation unit. The scheme discussed eliminates an expensive hydrolysis step often associated with the polymer process.

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Letter from Peter M. Kao to Railroad Commission of Texas, Gas Services Division, Pipeline Safety Section, dated received on Sep. 15, 1997.
FORMS-43 New Construction Report submitted by Celanese Pipeline Company to Railroad Commission of Texas, Gas Services Division, Pipeline Safety Section regarding construction of pipeline from Celanese to EVALCA, dated Sep. 10, 1997.
FORM T-4 Application for Permit to Operate a Pipeline in Texas submitted by Celanese Pipeline Company to Railroad Commission of Texas, Gas Services Division, Pipeline Safety Section regarding pipeline to transport acetic acid, vinyl acetate, and methyl acetate, dated Sep. 17, 1997.
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Pipeline and Gathering System Certification Renewal Form T-4C for Celanese Pipeline Company Permit No. 05452, dated Jul. 12, 2001.
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Letter from Deana L. Schepp, Celanese Transportation Regulations Specialist, to Mary L. McDaniel, Assistant Director Pipeline Safety, Railroad Commission of Texas, regarding pipelines containing methanol, acetic acid, vinyl acetate, methyl acrylate, ethyl acrylate, butyl acrylate, ethylene, glycol, and butanol, dated Aug. 4, 1999.
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Jones, Jane H., The Cativa TM Process for the Manufacture of Acetic Acid, Platinum Metals Rev., 2000, vol. 44, No. 3, 95-105.

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