Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1995-03-31
1997-02-04
O'Sullivan, Peter
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
540335, 540336, C07C24904, C07D20102, C07D20104, C07D20106
Patent
active
055999875
ABSTRACT:
An integrated process for producing cyclohexanone oxime, a caprolactam precursor, is provided wherein isopropanol is utilized to generate the hydrogen peroxide oxidizing agent. The acetone produced as a co-product is recycled back to the secondary alcohol by hydrogenation. Ammoximation of cyclohexanone is performed in the presence of water and an alcohol other than isopropanol such as methanol or t-butyl alcohol.
REFERENCES:
patent: 2819949 (1958-01-01), Keeler et al.
patent: 2869989 (1959-01-01), Keeler et al.
patent: 2871104 (1959-01-01), Rust
patent: 2949343 (1960-08-01), Hood et al.
patent: 4745221 (1988-05-01), Roffia et al.
patent: 4794198 (1988-12-01), Roffia et al.
patent: 4894478 (1990-01-01), Roffin et al.
patent: 5041652 (1991-08-01), Padovan et al.
Roffia et al, "Cyclohexanone Ammoximation: A Breakthrough in the 6- Caprolactam Production Process", New Developments in Selective Oxidation G. Centi and Trifiro eds. Elsevier, 1990, pp. 43-52.
Roffia et al., "A New Process for Cyclohexanonoxime", La Chimica & L' Industrin 72, 598-603 (1990).
Reddy et al., "Ammoximation of Cyclohexamine . . . ", J. Mol. Catal., 69, 383-392 (1991).
Clerici, "Catalytic Oxidation with Hydrogen Peroxide . . . ", in Heterogenous Catalysis and fine Chemicals III, M. Guismet et al., eds. Elsevier, pp. 21-33, 1993.
Crocco Guy L.
Jubin, Jr. John C.
Zajacek John G.
Arco Chemical Technology L.P.
Harper Stephen D.
O'Sullivan Peter
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