Insoluble polymers having functional groups containing chemicall

Details Insoluble polymers having functional groups containing chemicall Insoluble polymers having functional groups containing chemicall

1971-01-19

1978-07-04

Smith, Edward J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Cellular products or processes of preparing a cellular...

44 53, 252431R, 252431N, 252431P, 260604HF, 26049R, 526 19, 526 27, 526 48, 526 47, 521148, 568878, C08F 842, C08F 1236

Patent

active

040987272

ABSTRACT:
This specification discloses a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a catalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded thereto a metal of Group VIII of the Periodic Table. The metal can be, for example, rhodium, cobalt, or ruthenium. The olefin can contain more than one carbon-to-carbon double bond, may be an open chain or a cyclic olefin, and may be substituted. Further, the olefin may be contained in a refinery stream such as a cracked gasoline. The reaction may be carried out in the presence of a polar solvent.

REFERENCES:
patent: 1977634 (1934-10-01), Horsley
patent: 2827500 (1958-03-01), Bloecher, Jr. et al.
patent: 2897067 (1959-07-01), Sparks et al.
patent: 3081312 (1963-03-01), Long et al.
patent: 3455664 (1969-07-01), Rosscup et al.
patent: 3546009 (1970-12-01), Schneble et al.
patent: 3681021 (1972-08-01), Mikovsky et al.
patent: 3761458 (1973-09-01), Holler et al.
patent: 3900557 (1975-08-01), Strathodee

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