Insensitive polynitramine compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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149 92, C07D48710

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active

044852371

ABSTRACT:
The energetic compound 2,4,8,10-tetranitro-2,4,8,10-tetraazaspiro [5.5]undecane(TNSU) is disclosed. A general method of making 1,3-dinitroso-1,3-diazacycloalkanes in a one pot synthesis by the condensation of the diamine and formaldehyde, followed by conversion to the nitroso compound with nitrous acid. The general method also provides for the production of the tetranitroso precusor of TNSU.

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Mar. ed., Advanced Organic Chemistry, 2nd ed. (1977), McGraw Hill, p. 580.
Evans, Aust. J. Chem. 20 (1967), pp. 1643-1661.
Willer, R., "Synthesis and Characterization of a New Insensitive High Ene Polynitramine Compound, 2,4,8,10-tetranitro-2,4,8,10-tetraazaspiro[5.5]undecane(TNSU)", Naval Weapons Center, TP 6353, Mar. 1982.
Evans, R. F. , Aust. J. Chem., vol. 20 (1967), pp. 1643-1661.

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