Insecticidal d-cis, trans-chrysanthemates

Drug – bio-affecting and body treating compositions – Antigen – epitope – or other immunospecific immunoeffector – Fungus – except allergen – or component thereof or substance...

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Details

424285, 424306, A01N 922, A01N 924, A01N 928

Patent

active

039340236

ABSTRACT:
An insecticidal composition containing as an active ingredient an insecticidally effective amount of 10 to 30 % by weight of (+)-cis- and 70 to 90 % by weight of (+)-trans-chrysanthemate of the formula ##EQU1## wherein R is ##SPC1##
In which R.sub.1 is an allyl or propargyl group, R.sub.2 is a propargyl, benzyl or phenoxy group, R.sub.3 is a hydrogen atom or a methyl group, R.sub.4 is a hydrogen atom or an ethynyl group and Y is an oxygen atom or --CH=CH-- group; and
An insecticidal composition containing as an active ingredient an insecticidally effective amount of (a) at least one of above-mentioned (+)-cis,trans-chrysanthemates having said cis to trans ratio and (b) at least one of chrysanthemates prepared from a chrysanthemic acid having a cis to trans ratio different from that of the (+)-cis,trans-chrysanthemic acid moiety of the above formula (I) and an alcohol moiety of the above formula (I) having a structure different from that of the alcohol moiety of the (+)-cis,trans-chrysanthemates of above (a).
The (+)-cis,trans-chrysanthemates having said cis to trans ratio show an excellent insecticidal effect as well as a strong synergistic effect on the chrysanthemates of above (b).

REFERENCES:
patent: 3268551 (1966-08-01), Kuramoto et al.
patent: 3702333 (1972-11-01), Nakanishi et al.
patent: 3714153 (1973-01-01), Martel et al.
patent: 3723615 (1973-03-01), Okuno
patent: 3766218 (1973-10-01), Veda et al.
patent: 3767806 (1973-10-01), Rauch

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