Insecticidal compositions and methods of use employing imidaclop

Details Insecticidal compositions and methods of use employing imidaclop Insecticidal compositions and methods of use employing imidaclop

1997-11-17

1999-11-30

Robinson, Allen J.

Drug, bio-affecting and body treating compositions

Designated organic active ingredient containing

Phosphorus containing other than solely as part of an...

514341, A01N 4340, A01N 5726

Patent

active

059943319

DESCRIPTION:

BRIEF SUMMARY
The present invention relates to insecticidal compositions based on chloronicotinyl insecticides and synergists for insecticides.
Chloronicotinyl insecticides are known, for example from EP-OS (European Published Application) 192 060.
Synergists for insecticides are inhibitors of oxidases or cytochrome P 450 or increase the penetrability of cell membranes. They are known, for example, from Chemie der Pflanzenschutz- und Schadlingsbekampfungsmittel Volume 7K. Naumann Chemie der Synthetischen Pyrethroid-Insektizide Springer Verlag 1981 pages 3-5.
The present invention relates to mixtures of chloronicotinyl insecticides of the formula (I) ##STR3## in which R.sup.1 represents C.sub.1 -C.sub.5 -alkyl, --CH.sub.2 --CH.sub.2 -- or ##STR4## X represents an NH group, NCH.sub.3 group or represents sulphur, Y represents nitrogen or a CH group and [M-Gusathion]; 3-carbonitrile [AC 303, 630]; [CGA 106 630; Polo]; [Triazuron]; xathiepine 3-oxide [Endosulfan; Thiodan]; mide [Cesar; Hexythiazox]; hionopyrazole [Fipronil]; 1-propenyl)-2,2-dimethyl-cyclopropane-carboxylate [Tefluthrin; Force]; [Amitraz]; [RH 5992]; 1,1,2,3,3,3-hexafluoropropoxy)phenyl]-aminocarbonyl]-2,6-difluorobenzamide [Match]; 498]; H)-one [Chess].
Preference is given to novel mixtures of the above specified synergists with chloronicotinyl insecticides of the following structural formulae: ##STR5##
Particular preference is given to novel mixtures of the abovementioned synergists with chloronicotinyl insecticides of the formulae: ##STR6##
The novel active compound mixtures of chloronicotinyl insecticides with the above-specified synergists can be converted into the customary formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, active-compound-impregnated natural and synthetic materials, very fine encapsulations in polymeric substances and in coating compositions for seed, furthermore in formulations with smokes, such as fumigating cartridges, fumigating cans, fumigating coils and the like, and also ULV cold mist and warm mist formulations.
These formulations are prepared in a known manner, for example by mixing the active compounds with extenders, that is, liquid solvents, pressurized liquefied gases and/or solid carriers, optionally with the use of surface-active agents, that is, emulsifying agents and/or dispersing agents, and/or foam-forming agents. In the case of the use of water as an extender, organic solvents can, for example, also be used as auxiliary solvents. As liquid solvents, there are suitable in the main: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example mineral oil fractions, alcohols, such as butanol or glycol as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulphoxide, as well as water; by liquefied gaseous extenders or carriers are meant liquids which are gaseous at ambient temperature and under atmospheric pressure, for example aerosol propellant, such as halogenated hydrocarbons as well as butane, propane, nitrogen and carbon dioxide; as solid carriers there are suitable: for example ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and silicates; as solid carriers for granules there are suitable: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; as emulsifying and/or foam-forming agents there are suitable: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyox

REFERENCES:
patent: 4849432 (1989-07-01), Shiokawa et al.
The Pesticide Manual 10th edition, (month unavailable) 1994.
R. Wegeler (Ed.) K.Naumann, "Chemie der Pflanzenschutz-und Schadlingsbekampfungsmittel", Band 7, Chemie der synthetischen Pyrethroid-Insektizide (month unavailable) 1981.
Tomlin, The Pesticide Manual, 10.sup.th Ed. (1994) pp. 673, 674.

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