Incremental printing of symbolic information – Ink jet – Fluid or fluid source handling means
Reexamination Certificate
1999-12-27
2002-03-05
Le, N. (Department: 2861)
Incremental printing of symbolic information
Ink jet
Fluid or fluid source handling means
C347S095000
Reexamination Certificate
active
06352340
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to an ink jet printing method which employs an additive for a pigmented ink jet ink to improve printing reliability.
BACKGROUND OF THE INVENTION
Ink jet printing is a non-impact method for producing images by the deposition of ink droplets on a substrate (paper, transparent film, fabric, etc.) in response to digital signals. Ink jet printers have found broad applications across markets ranging from industrial labeling to short run printing to desktop document and pictorial imaging. The inks used in ink jet printers are generally classified as either dye-based or pigment-based.
A dye is a colorant which is molecularly dispersed or solvated by a carrier. The carrier can be a liquid or a solid at room temperature. A commonly used carrier is water or a mixture of water and organic co-solvents. Each individual dye molecule is surrounded by molecules of the carrier. In dye-based inks, no particles are observable under the microscope. Although there have been many recent advances in the art of dye-based ink jet inks, such inks still suffer from deficiencies such as low optical densities on plain paper and poor light-fastness. When water is used as the carrier, such inks also generally suffer from poor water fastness.
In pigment-based inks, the colorant exists as discrete particles. These pigment particles are usually treated with addenda known as dispersants or stabilizers which serve to keep the pigment particles from agglomerating and settling out of the carrier. Water-based pigmented inks are prepared by incorporating the pigment in the continuous water phase by a milling and dispersing process. Pigmented inks require a water soluble dispersant in the pigment slurry during the milling process. Such a dispersant is necessary to produce a colloidally stable mixture and an ink that can be “jetted” reliably without clogging the print head nozzles.
Dispersing agents in an ink jet ink have the dual function of helping to break down pigments to sub-micron size during the milling process and of keeping the colloidal dispersion stable and free from flocculation for a long period of time.
A requirement in wide format ink jet printers is the delivery of at least 500 ml of ink through a printhead before nozzles begin to fail to fire ink droplets. Reproducible quantities of ink delivered prior to print cartridge failure (ink reliability) and particle size stability, over time, have been problems encountered with ink jet inks containing pigments as colorants and anionic dispersants.
U.S. patent application Ser. No. 09/351,614, filed Jul. 12, 1999, entitled “Color Pigmented Ink Jet Ink Set” discloses a typical ink jet pigmented ink. However, there is a problem with print cartridges containing those inks in that the print reliability over an extended period of time is not as good as one would desire.
U.S. Pat. No. 5,855,656 relates to an ink jet ink containing a cationic fluorocarbon material. There is a disclosure in this patent that a nonionic surfactant maybe used such as Tergitol TMN-10®. However, there is a problem with this combination used in a pigmented ink with an anionic dispersant in that the dispersion is not stable, i.e., the pigment will precipitate out.
It is an object of this invention to provide an ink jet printing method which employs an additive for a pigmented ink jet ink which would improve the print reliability. It is another object of this invention to provide an ink jet printing method which employs an additive for a pigmented ink jet ink which would be useful with a variety of pigments. It is still another object of this invention to provide an ink jet printing method which employs an additive for a pigmented ink jet ink which would not affect the dispersion stability.
SUMMARY OF THE INVENTION
These and other objects are achieved in accordance with this invention which relates to an ink jet printing method, comprising the steps of:
A) providing an ink jet printer that is responsive to digital data signals;
B) loading the printer with ink-receptive substrates;
C) loading the printer with an ink jet ink composition comprising from about 30 to about 90% by weight of water, from about 0.5 to about 30% by weight of a pigment, from about 0.125 to about 7.5% by weight of an anionic dispersant, from about 0.05 to about 2% by weight of an ethoxylated trimethylnonanol, and from about 10 to about 50% by weight of a humectant comprising a polyhydric alcohol; and
D) printing on an ink-receptive substrate using the ink jet ink in response to the digital data signals.
Use of the ethoxylated trimethylnonanol in the inks employed in this invention greatly increases the amount of ink that may be delivered before print nozzles begin to fail.
DETAILED DESCRIPTION OF THE INVENTION
As noted above, the ink jet ink composition employed in the process of the invention contains the ethoxylated trimethylnonanol at a concentration of from about 0.05 to about 2.0 weight percent. In a preferred embodiment, the concentration of the ethoxylated trimethylnonanol is from about 0.075 to about 1.0 weight percent. In another preferred embodiment of the invention, the ethoxylated trimethylnonanol has the formula C
12
H
25
O(CH
2
CH
2
O)
n
H, where n is from about 3 to about 10, and is made through the reaction of 2,6,8-trimethyl-4-nonanol with ethylene oxide. These materials are sold commercially as Tergitol® TMN-3, -6 and -10 (Union Carbide Corp.).
In the present invention, any of the known organic pigments can be used. Pigments can be selected from those disclosed, for example, in U.S. Pat. Nos. 5,026,427; 5,085,698; 5,141,556; 5,160,370 and 5,169,436, the disclosures of which are hereby incorporated by reference. The exact choice of pigment will depend upon the specific color reproduction and image stability requirements of the printer and application. For four-color printers, combinations of cyan, magenta, yellow and black (CMYK) pigments are used. In a preferred embodiment, the pigment set is cyan pigment, C.I. Pigment Blue 15:3; quinacridone magenta, C.I. Pigment Red 122; C.I. Pigment Yellow 155; and carbon black, C.I. Pigment Black 7.
A humectant is added to the composition employed in the process of the invention to help prevent the ink from drying out or crusting in the orifices of the ink jet printhead. Polyhydric alcohols useful in the composition of the invention for this purpose include, for example, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, tetraethylene glycol, polyethylene glycol, glycerol, 2-methyl-2,4-pentanediol, 1,2,6-hexanetriol and thioglycol. As noted above, the humectant is employed in a concentration of from about 10 to about 50% by weight. In a preferred embodiment, diethylene glycol or a mixture of glycerol and diethylene glycol is employed a concentration of between 10 and 20 wt. %.
A co-solvent can also be employed in the composition employed in the process of the invention. The selection of a co-solvent depends on the requirements of the specific application, such as desired surface tension and viscosity, the selected pigment, drying time of the pigmented ink jet ink, and the type of paper onto which the ink will be printed. Representative examples of water-soluble co-solvents that may be selected include (1) alcohols, such as methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, sec-butyl alcohol, t-butyl alcohol, iso-butyl alcohol, fiirftiryl alcohol, and tetrahydroflirfuryl alcohol; (2) ketones or ketoalcohols such as acetone, methyl ethyl ketone and diacetone alcohol; (3) esters, such as ethyl acetate, ethyl lactate, ethylene carbonate and propylene carbonate; and (4) sulfur-containing compounds such as dimethyl sulfoxide and tetramethylene sulfone.
Dispersants which are used in the composition employed in the process of the invention include sodium dodecyl sulfate, acrylic and styrene-acrylic copolymers, such as those disclosed in U.S. Pat. Nos. 5,085,698 and 5,172,133, and styrenics, such as those disclosed in U.S. Pat. No. 4,597,794. Other patents referred to above
Erdtmann David
Kocher Thomas E.
Martin Thomas W.
Pitt Alan R.
Cole Harold E.
Eastman Kodak Company
Le N.
Welker Matthew T.
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