Ink jet printing

Incremental printing of symbolic information – Ink jet – Ejector mechanism

Reexamination Certificate

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Details

C347S024000

Reexamination Certificate

active

06382763

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to apparatus and methods, such as used in ink jet printing, wherein liquid which contains substances suspended therein is forced or drawn by gas pressure through a tube or opening having a very small diameter.
BACKGROUND OF THE INVENTION
In ink jet printing, typically, ink is applied in a pattern to a substrate such as a sheet of paper, a label, the surface of an article, or the like. The ink is forced at high velocity through a nozzle or head, and travels a short distance through the ambient atmosphere outside the nozzle or head to the substrate. The pattern which the ink forms on the substrate is determined by the configuration of minute openings in the head or nozzle through which the ink emerges.
The force impelling the ink is provided by gas under pressure, typically compressed air. The gas is fed from a source, such as a tank or cylinder which maintains the gas under pressure, into one end of a line or tube the other end of which is connected to the nozzle or head.
Existing ink jet printing systems have exhibited several operational drawbacks that operators have up to now had to tolerate. One is that the nozzles periodically become clogged, requiring the system to be shut down so that a clogged nozzle can be cleaned or replaced with an unclogged nozzle. This drawback obviously prevents the system from operating for the time that it is shut down for cleaning and/or replacement of the nozzle. It can also lead a certain proportion of the ink jet-printed product being printed with only mediocre quality, as the nozzle becomes clogged only gradually resulting in gradually reduced sharpness and definition in the pattern that is printed onto the substrate.
This drawback has typically been dealt with by incorporating one or more filters into the lines carrying the vehicle, the concentrate, the gas, and/or the ink/gas mixture. However, this only transfers the site of the clogging from the nozzle to the filter(s), so that it is still necessary periodically to shut down the system to clean and/or replace one or more filter(s).
Another drawback is that the amount of vehicle required for satisfactory printing increases over the course of operation. Ink jet printing systems typically contain means for monitoring the viscosity of the ink, and means for increasing the amount of vehicle fed into the system relative to the amount of concentrate when the viscosity of the ink has increased excessively, thereby attempting to ensure that the viscosity of the ink remains sufficiently low that the ink can flow and can be printed as desired. Conventional ink jet printing systems often draw more and more vehicle, because the ink viscosity gradually increases until a point is reached at which either the filter or nozzle becomes clogged, or the ink is otherwise too viscous to permit satisfactory operation.
Thus, there remains a need in this field for a solution to the problem of clogging of the nozzle and/or filters, and to the problem of excessive vehicle consumption in the course of operation of the system. These problems characterize other devices wherein liquid vehicle contains dispersed therein material which can clog the system, and a solution to these problems would be useful in such contexts as well.
BRIEF SUMMARY OF THE INVENTION
One aspect of the present invention is a method for ink jet printing, comprising
(A) feeding gas through a feed line which terminates with an opening;
(B) feeding into said feed line ink concentrate which contains at least one component whose particle size increases upon contact with water;
(C) feeding into said feed line a vehicle which forms ink when combined with said ink concentrate;
(D) combining said ink concentrate and said vehicle in said feed line to form ink; and
(E) applying sufficient pressure to said feed line to expel said ink out said opening; wherein said gas and said vehicle contain no water or have a combined water content insufficient to cause said increase in particle size.
Another aspect of the present invention is apparatus for ink jet printing, comprising:
(a) a gas source containing gas;
(b) an ink concentrate source which contains ink concentrate comprising at least one component which increases in particle size when contacted with water;
(c) a vehicle source containing vehicle which forms ink when combined with said concentrate;
(d) a feed line connected to said gas source and ending in an opening, through which feed line said gas can flow from said gas source to said opening;
(e) lines connecting said ink concentrate source and said vehicle source to said feed line; and
(f) means for controllably passing gas from said gas source through said feed line, combining said ink concentrate and said vehicle in said line to form ink, and expelling said ink out said opening, wherein said gas and said vehicle contain no water or together have a water content insufficient to cause said increase in particle size.
By virtue of this discovery, it is possible to carry out ink jet printing using this method and this apparatus without incorporating any filters in any of the lines connecting the gas source, the concentrate source, and the vehicle source to the opening.
In preferred embodiments of this invention, the ink concentrate contains nitrocellulose, whose particle size increases upon contact with water as it tends to form gels. Nitrogen, containing no water or only up to 4.0 ppm or 0.0004 wt. % water, is the preferred gas.
DETAILED DESCRIPTION OF THE INVENTION
It will be understood that references herein to “water” include water in any physical state, including water vapor.
It has been discovered that in an ink jet printing system wherein the ink concentrate contains one or more components whose particle size increases upon contact with water (i.e. water vapor or liquid or less often solid water), the aforementioned problems are avoided by forming and spraying the ink with components which contain no water or which contain in the aggregate only a small amount of water, such as up to 60.0 ppm (0.0060 wt. %) water. The aforementioned increase of particle size is irrespective of the particular reason; thus, depending on the component, contact with water might increase particle size through formation of gels, through flocculation or agglomeration, through oligomerization or polymerization, or through the onset of some other chemical reaction leading to increased particle size in the concentrate or the ink.
This discovery is unexpected, particularly in that the prior art has taught overcoming the clogging problems by use of combinations of feed gas and intentionally introduced water.
Suitable gases include nitrogen, argon, and other gases which are inert to the vehicle and to the components of the ink, as well as mixtures of such gases.
Gas such as nitrogen which is either free of water or contains only up to 4.0 ppm or 0.0004 wt. % of water is preferred and is commercially available (e.g. from Praxair, Inc.) in a form which as supplied already has the desired low water content. Alternatively, one can employ gas which as supplied contains more than the indicated maximum water content, provided that before the gas is contacted with the ink concentrate it is treated to remove all the water or to remove at least enough water that the resulting gas together with the vehicle contains no more than 0.0060 wt. % water. Suitable treatment procedures include physical and chemical adsorbents, and cold traps.
It will be recognized here that the ink concentrate should also contain little or no water, such that the aggregate water content of gas, vehicle and concentrate does not exceed about 0.0060 wt. %, but in practice the concentrate will have already attained that low water content by virtue of interaction having already taken place with the component(s) of the concentrate that increase in particle size upon contact with water.
The ink is comprised in part of functional components such as resin (which cures or dries on the substrate to form the final relatively permanent pattern), colorant, thickener, suspending

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