Initiator systems containing vanadium tetrachloride for the (co)

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522 66, 522184, 522186, 522188, 526139, 526141, 526142, 526143, 526144, 526237, 502227, C08F 250, C08F 420, C08F 1004

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active

060158417

ABSTRACT:
This invention relates to an initiator system for the polymerization of isoolefins having 4 to 16 carbon atoms, optionally with monomers polymerizable with isoolefins, the system consisting of or one or more aromatic or heteroaromatic, polycyclic hydrocarbons and an aged, organic solution of vanadium tetrachloride, wherein the concentration of the vanadium tetrachloride is 0.01 mmol to 500 mmol per liter of solvent and the molar ratio of aged vanadium tetrachloride to polycyclic hydrocarbons is in the range from 100:1 to 1:100.
It is possible by means of the initiator system according to the invention to produce polyisoolefins, in particular butyl rubbers, at relatively high temperatures with only a low gel content and of a sufficiently high molecular weight.

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patent: 4871523 (1989-10-01), Datta et al.
patent: 5473029 (1995-12-01), Osman
patent: 5516862 (1996-05-01), Yamamoto et al.

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