Initiated peroxidation of secondary carbon in alkanes and cycloa

Details Initiated peroxidation of secondary carbon in alkanes and cycloa Initiated peroxidation of secondary carbon in alkanes and cycloa

1992-07-17

1993-06-15

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568568, 568570, 568571, C07C40902, C07C40914

Patent

active

052200752

ABSTRACT:
A secondary carbon atom in an alkane, including alkyl groups attached to aromatic rings, or cycloalkane is oxidized by molecular oxygen to the corresponding hydroperoxide in the absence of a catalyst. The oxidation is carried out in the presence of a tertiary hydroperoxide initiator which provides the free radicals needed to maintain the reaction. The amount of tertiary alcohol in the initiator is limited.

REFERENCES:
patent: 3987115 (1976-10-01), Zajacek et al.
patent: 4341907 (1982-07-01), Zelonka

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