Inhibitor for prevention of braze migration in solid oxide...

Chemistry: electrical current producing apparatus – product – and – Fuel cell – subcombination thereof – or method of making or... – Fuel cell with solid electrolyte

Reexamination Certificate

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Details

C429S482000, C429S507000, C429S508000, C429S509000

Reexamination Certificate

active

07855030

ABSTRACT:
During manufacture of an SOFC assembly, an inhibitor is included to prevent migration of silver braze during subsequent use of the SOFC assembly. The inhibitor may take any of several forms, either individually or in combination. Inhibitors comprehended by the present invention include, but are not limited to: a) a mechanical barrier that can be printed or dispensed onto one or more SOFC stack elements around the braze areas to prevent mechanically-driven migration; b) an electrically insulating feature in the electrolyte or interlayer over the electrolyte layer in the seal margins to prevent electrical potential-driven migration; and 3) chemical modification of the braze itself as by addition of an alloying metal such as palladium.

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Kim Vu, “Silver Migration—The Mechanism and Effects on Thick-Film Conductors,” Material Science Engineering 234, Spring 2003, College of Engineering, San Jose University.
European Search Report dated Aug. 23, 2010.
Zhenguo Yang et al: “Chemical Compatibility of Barium-Calcium-Aluminosilicate-Based Sealing Glasses with the Ferritic Stainless Steel Interconnect in SOFCs”; Journal of the Electrochemical Society, vol. 150, No. 8, Jun. 23, 2003, pp. A1095-A1101, XP002597307.

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