Inhibition of corrosion in aqueous systems

Details Inhibition of corrosion in aqueous systems Inhibition of corrosion in aqueous systems

1998-08-19

2001-02-13

Warden, Sr., Robert J. (Department: 1744)

Chemical apparatus and process disinfecting, deodorizing, preser

Process disinfecting, preserving, deodorizing, or sterilizing

Maintaining environment nondestructive to metal

C422S012000

Reexamination Certificate

active

06187262

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to the treatment of water to inhibit scale and control corrosion of metals in contact with aqueous systems. More particularly, the present invention relates to the use of tetrazolium salts to inhibit scale or prevent corrosion of ferrous-based metals in contact with aqueous systems.
BACKGROUND OF THE INVENTION
In industrial cooling systems, water such as from rivers, lakes, ponds, etc., is employed as the cooling media for heat exchangers. The cooling water from heat exchangers is typically passed through a cooling tower, spray pond or evaporative system prior to discharge or reuse. In these systems, the cooling effect is achieved by evaporating a portion of the water passing through the system. Because of the evaporation which takes place during cooling, dissolved materials in the water become concentrated, making the water more corrosive.
In cooling systems, corrosion causes two basic problems. The first and most obvious is the failure of equipment, resulting in replacement costs and plant downtime. Also, decreased plant efficiency occurs due to the loss of heat transfer. The accumulation of corrosion products causes heat exchanger fouling, resulting in the loss of heat transfer.
Ferrous-based metals, e.g., iron metal and metal alloys containing iron (mild steel), are routinely used in the construction of cooling systems due to their low cost and availability. As the system water passes over or through these ferrous-based metal containing devices, they are subjected to corrosion processes. Corrosion inhibitors are generally added as part of a water treatment program in cooling systems to prevent and inhibit the corrosion of ferrous-based metal containing devices.
Molybdates, zinc, phosphates or polyphosphates, and phosphonates have been used to inhibit the corrosion of ferrous-based metals in contact with the system water of cooling systems. Each treatment, however, presents certain drawbacks.
There exists a need, therefore, for a more environmentally acceptable corrosion inhibitor of ferrous-based metals in contact with aqueous systems.
Preventing the corrosion and scaling of industrial heat transfer equipment is essential to the efficient and economical operation of a cooling water system. Excessive corrosion of metallic surfaces can cause the premature failure of process equipment, necessitating downtime for the replacement or repair of the equipment. Additionally, the buildup of corrosion products on the heat transfer surface reduces efficiency, thereby limiting production or requiring downtime for cleaning.
SUMMARY OF THE INVENTION
The present invention provides an effective method for controlling corrosion of metals, particularly ferrous-based metals in contact with aqueous systems.
The method of the present invention comprises treating industrial waters with a tetrazolium salt of the general formula:
wherein R
1
, R
2
and R
3
can be various organic and inorganic substituents, e.g., from the group consisting of lower alkyl, aryl, aralkyl, and heterocyclic substituted aryl with the proviso that neither R
1
, R
2
or R
3
contain more than 14 carbon atoms, and n may be 1 or 2.
The compounds may contain positive or negative counter ions in order to balance the charges on the above structure. Chemical or electrochemical reduction of this type of compound produces tetrazolinyls and formazans that readily adsorb on metal surfaces and provide films for corrosion protection.
In aqueous systems, the following corrosion reactions of metals such as steel occur:
Fe→Fe
2+
+2e
−
Fe(OH)
2
+OH
−
→Fe(OH)
3
+e
−
When tetrazolium compounds possessing redox potentials higher than that of the corroding metals or alloys are employed, reduction of tetrazolium molecules readily occur on the steel surface to form insoluble materials and, hence, prevent steel from further corrosion.
The invention will now be further described with reference to a number of specific examples which are to be regarded solely as illustrative and not as restricting the scope of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The film formation and corrosion inhibition activity of the treatment of the present invention was evaluated with a Beaker Corrosion Test Apparatus (BCTA). The BCTA includes a beaker equipped with an air/CO
2
sparge, low carbon steel (LCS) coupon, electrochemical probe and magnetic stirrer. The beaker is immersed in a water bath for temperature control. Electrochemical corrosion data were obtained using linear polarization resistance technique. All tests were conducted at 120° F., 400 RPM for 18 hours.
Compounds Tested
Compound
R
1
R
2
R
3
n
NBT
CH
3
OC
6
H
3
NO
2
C
6
H
4
C
6
H
5
2
INT
IC
6
H
4
NO
2
C
6
H
4
C
6
H
5
1
TZV
C
10
H
7
C
6
H
5
C
6
H
5
1
TTC
C
6
H
5
C
6
H
5
C
6
H
5
1
NBT: 3,3′(3,3′-dimethoxy-4,4′-biphenylene)-bis-[2-(p-nitrophenyl)-5-phenyl-2H-tetrazolium chloride]
INT: 2-(4-iodophenyl)-3-(4-nitrophenyl)-5-phenyl tetrazolium chloride
TZV: 2,5-diphenyl-3-(1-naphthyl)-2H-tetrazolium chloride
TTC: 2,3,5-triphenyl-2H-tetrazolium chloride


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Horner et al., Werkstoffe und Korrosion, 29, 654-664 (1978), which is includes an English language abstract.
Horner et al., Werkstoffe und Korrosion, 36, 545-553 (1985), which includes an English language abstract.
Abo El-Khair et al., “Inhibiting Effect of Triphenyl Tetrazolium Chloride on the Corrosion of Aluminum in HCI”Corrosion Prevention&Control, 1981, p. 7-10.
Aleya et al., “Inhibition of the Acid Corrosion of Iron with Triphenyl Tetrazolium Chloride,”Corrosion Science, 1982, p. 717-22.

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