Inhibited precious metal catalyzed organopolysiloxane compositio

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 21, 528 31, 528 32, 525478, C08G 7706

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active

046705317

ABSTRACT:
There are provided curable compositions, comprising (a) an organopolysiloxane base polymer, (b) an organohydrogenpolysiloxane crosslinking agent, (c) an effective amount of precious metal containing catalyst, and (d) and azo compound wherein at least one --N.dbd.N-- moiety is not part of a cyclic structure, and preferably is alpha to an electron withdrawing group such as carbonyl, in an amount effective to inhibit reaction of said organopolysiloxane base polymer and said organohydrogenpolysiloxane crosslinking agent. Articles of manufacture as well as methods for preparation of such compositions and articles are also provided.

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